A ruthenium-inserted hydrotalcite (Ru-HT) heterogeneous catalyst: kinetic studies on the selective hydrogenation of carbon dioxide to formic acid-Reference-Cited by-同舟云学术

A ruthenium-inserted hydrotalcite (Ru-HT) heterogeneous catalyst: kinetic studies on the selective hydrogenation of carbon dioxide to formic acid

Published:2021 Issue:16 Volume:2 Page:5443-5452
ISSN:2633-5409
Container-title:Materials Advances
language:en
Short-container-title:Mater. Adv.

Author:

Maru Minaxi S.¹²³^ORCID,Ram Sanwala¹⁴,Khan Noor-ul H.¹⁴^ORCID,Shukla Ram S.¹⁴

Affiliation:

1. Inorganic Materials and Catalysis Division, Council of Scientific and Industrial Research (CSIR), Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar, 364002, Gujarat, India

2. Inorganic Chemistry Division, Department of Chemistry, Saurashtra University, Rajkot, 360005, Gujarat, India

3. Department of Chemistry, Indian Institute of Teacher Education (IITE), Gandhinagar, 382016, Gujarat, India

4. Academy of Scientific and Innovative Research (AcSIR), Council of Scientific and Industrial Research (CSIR), Central Salt and Marine Chemicals Research Institute, G. B. Marg, Bhavnagar, 364002, Gujarat, India

Abstract

Kinetic studies have been carried out for an effective and recyclable heterogeneous Ru-HT catalyst for CO2 hydrogenation to formic acid without a base. A TON of 11 389 was successfully achieved in 24 h at 60 °C and 60 bar pressure in a MeOH:H2O mixed solvent.

Funder

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Microbiology

Link

http://pubs.rsc.org/en/content/articlepdf/2021/MA/D1MA00431J

Reference78 articles.

1. CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

2. Catalysis for the Valorization of Exhaust Carbon: from CO2 to Chemicals, Materials, and Fuels. Technological Use of CO2

3. Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries