Glass-amorphous alkali-ion solid electrolytes and their performance in symmetrical cells

Author:

Braga M. Helena12345,Murchison Andrew J.12345,Ferreira Jorge A.678,Singh Preetam9101112,Goodenough John B.9101112

Affiliation:

1. CEMUC

2. Engineering Physics Department

3. Engineering Faculty

4. University of Porto

5. 4200-465 Porto

6. Energy and Geology National Laboratory (LNEG)

7. 4466-901 S. Mamede de Infesta

8. Portugal

9. Texas Materials Institute and the Materials Science and Engineering Program

10. The University of Texas at Austin

11. Austin

12. USA

Abstract

Precursors of the crystalline antiperovskites A3−xHxOCl (A = Li or Na and 0 < x < 1) can be rendered glass/amorphous solid Li+ or Na+ electrolytes by the addition of water to its solvation limit with/without the addition of a small amount of an oxide or hydroxide.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Reference4 articles.

1. Solid State Electrochemistry, ed. P. B. Bruce, Cambridge University Press, 1995, Table 2.1, p. 24

2. Novel Li3ClO based glasses with superionic properties for lithium batteries

3. Diffusion in Solids Fundamentals, Methods, Materials, Diffusion-Controlled Processes, ed. H. Mehrer, Springer Series in Solid-State Sciences, 1st edn, 2007, vol. 155

4. Modern Electroplating, ed. M. Schlesinger, Wiley-Interscience publication, J. Wiley & Sons, Inc., 4th edn, 2000

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