Supported Ru olefin metathesis catalysts via a thiolate tether

Author:

Renom-Carrasco Marc12345ORCID,Mania Philipp12345,Sayah Reine12345,Veyre Laurent12345,Occhipinti Giovanni6789ORCID,Gajan David101112135,Lesage Anne101112135ORCID,Jensen Vidar R.6789ORCID,Thieuleux Chloé12345ORCID

Affiliation:

1. University of Lyon

2. Institute of Chemistry of Lyon

3. Laboratory C2P2 UMR 5265-CNRS-University Lyon 1-CPE Lyon

4. 69616 Villeurbanne

5. France

6. Department of Chemistry

7. University of Bergen

8. N-5007 Bergen

9. Norway

10. Institut des Sciences Analytiques UMR 5280 (CNRS/Université Lyon 1/ENS Lyon)

11. Université de Lyon

12. Centre de RMN à Très Hauts Champs

13. 69100 Villeurbanne

Abstract

Ruthenium alkylidene complexes can be successfully immobilized on hybrid mesostructured silica via thiolate tethers to give heterogeneous, thiolate-coordinated olefin metathesis catalysts.

Funder

Norges Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

1. Handbook of Metathesis , ed. R. H. Grubbs , Wiley-VCH , Weinheim , 2003 , vol. 1

2. Olefin Metathesis at the Dawn of Implementation in Pharmaceutical and Specialty-Chemicals Manufacturing

3. Heterogeneous olefin-metathesis: Comparative perspective of the activity with respect to unsaturated fatty acid methyl esters

4. Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization

5. M. R. Buchmeiser , Immobilization of olefin metathesis catalysts , in Olefin Metathesis: Theory and Practice , ed. K. Grela , Wiley-VCH , Weinheim , 2014

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