Theoretical study on the mechanism, chemo- and enantioselectivity of the Ag- <i>vs.</i> Rh-catalyzed intramolecular carbene transfer reaction of diazoacetamides-Reference-Cited by-同舟云学术

Theoretical study on the mechanism, chemo- and enantioselectivity of the Ag- vs. Rh-catalyzed intramolecular carbene transfer reaction of diazoacetamides

Published:2022 Issue:28 Volume:12 Page:18197-18208
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Song Qingmin¹,Wu Jiayi¹,Tzoukras Nikolaos V.²,Wu Yong¹^ORCID,Nolan Steven P.²^ORCID

Affiliation:

1. Department of Chemistry Northeast Normal University, Changchun 130024, China

2. Department of Chemistry and Center for Sustainable Chemistry, Ghent University, Krijgslaan 281, S3, Ghent 9000, Belgium

Abstract

DFT calculations reveal the mechanism, as well as the origins of chemoselectivity and enantioselectivity in the Ag vs. Rh catalyzed intramolecular carbene transfer reaction.

Funder

Education Department of Jilin Province

Central University Basic Research Fund of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D2RA01298G

Reference44 articles.

1. Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

2. Reactivity and Selectivity in Catalytic Reactions of Enoldiazoacetamides. Assessment of Metal Carbenes as Intermediates

3. General Approach to Nitrogen-Bridged Bicyclic Frameworks by Rh-Catalyzed Formal Carbenoid Insertion into an Amide C–N Bond

4. Silver and platinum-catalysed addition of O–H and N–H bonds to allenes

5. Coinage Metal-Assisted Synthesis of Heterocycles

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1. Metal-Carbenoid-Mediated Selective Transformation: Experimental and DFT Studies of Ag, Pd, and Rh with Enaminones and Diazoesters;ACS Catalysis;2024-08-26

2. Highly electrophilic silver carbenes;Chemical Communications;2022

3. Correction: theoretical study on the mechanism, chemo- and enantioselectivity of the Ag- vs. Rh-catalyzed intramolecular carbene transfer reaction of diazoacetamides;RSC Advances;2022