A flexible cofacial Fe porphyrin dimer as an extremely efficient and selective electrocatalyst for the CO2 to CO conversion in non-aqueous and aqueous media

Author:

Mohamed Eman A.1ORCID,Zahran Zaki N.12,Naruta Yoshinori3

Affiliation:

1. Department of Materials Science and Technology, Faculty of Engineering, Niigata University, 8050 Ikarashi-2, Niigata 9050-2181, Japan

2. Chemistry Department, Faculty of Science, Tanta University, Tanta 511111, Egypt

3. Institute of Science and Technology Research, Centre for Chemical Energy Conversion Res., Chubu University, Kasugai 487-8501, Japan

Abstract

A cofacial iron porphyrin dimer with a flexible structure (f-Fe2PD) showed extremely efficient CO2-to-CO conversion in aqueous and nonaqueous media compared to the one with a rigid structure (r-Fe2PD) and reported catalysts.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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