Electronic band structure of 1D π–d hybridized narrow-gap metal–organic polymers

Author:

Frezza Federico12ORCID,Schiller Frederik34ORCID,Cahlík Aleš1ORCID,Ortega Jose Enrique345ORCID,Barth Johannes V.6,Arnau Andres734ORCID,Blanco-Rey María74ORCID,Jelínek Pavel18,Corso Martina34ORCID,Piquero-Zulaica Ignacio6ORCID

Affiliation:

1. Institute of Physics, Czech Academy of Sciences, 16200 Prague, Czech Republic

2. Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague Brehová 78/7, 11519 Prague 1, Czech Republic

3. Centro de Física de Materials CSIC/UPV-EHU-Materials Physics Center, 20018 San Sebastián, Spain

4. Donostia International Physics Center (DIPC), 20018 Donostia-San Sebastián, Spain

5. Departmento de Física Aplicada I, Universidad del País Vasco, 20018 San Sebastián, Spain

6. Physics Department E20, Technical University of Munich, 85748 Garching, Germany

7. Departamento de Polímeros y Materiales Avanzados: Física, Química y Tecnología, Universidad del País Vasco UPV/EHU, 20080, Donostia-San Sebastián, Spain

8. Regional Centre of Advanced Technologies and Materials, Palacký University, 78371 Olomuc, Czech Republic

Abstract

On-surface synthesis of well-aligned, atom-thick metal–organic polymers and experimental determination of their near Fermi level dispersive and weakly dispersive bands induced by the efficient hybridization of atomic and molecular orbitals.

Funder

Agencia Estatal de Investigación

Eusko Jaurlaritza

Consejo Superior de Investigaciones Científicas

Euskal Herriko Unibertsitatea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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