Decomplexation as a rate limitation in the thiol-Michael addition of N-acrylamides-Reference-Cited by-同舟云学术

Decomplexation as a rate limitation in the thiol-Michael addition of N-acrylamides

Published:2020 Issue:32 Volume:18 Page:6364-6377
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Brown Joseph S.¹²³⁴^ORCID,Ruttinger Andrew W.¹²³⁴^ORCID,Vaidya Akash J.¹²³⁴,Alabi Christopher A.¹²³⁴^ORCID,Clancy Paulette⁵⁶⁷⁴^ORCID

Affiliation:

1. Robert F. Smith School of Chemical and Biomolecular Engineering

2. Cornell University

3. Ithaca

4. USA

5. Department of Chemical and Biomolecular Engineering

6. The Johns Hopkins University

7. Baltimore

Abstract

Experimental and computational agreement highlights rate-limiting “product decomplexation” and functional group effects in the thiol-Michael addition, utilized for sequence-defined oligomers.

Funder

Cornell University

National Science Foundation

Army Research Office

Johns Hopkins University

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB00726A

Reference84 articles.

1. Thiol-Ene Click Chemistry

2. The power of thiol-ene chemistry

3. Thiol-enes: Chemistry of the past with promise for the future

4. Thiol-ene “click” reactions and recent applications in polymer and materials synthesis

5. Vulcanization and crosslinking in elastomers

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