Sub-Doppler infrared spectroscopy of resonance-stabilized hydrocarbon intermediates: ν3/ν4 CH stretch modes and CH2 internal rotor dynamics of benzyl radical-Reference-Cited by-同舟云学术

Sub-Doppler infrared spectroscopy of resonance-stabilized hydrocarbon intermediates: ν3/ν4 CH stretch modes and CH2 internal rotor dynamics of benzyl radical

Published:2017 Issue:44 Volume:19 Page:29812-29821
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kortyna A.¹²³⁴⁵^ORCID,Samin A. J.⁶⁷⁸⁵,Miller T. A.⁶⁷⁸⁵^ORCID,Nesbitt D. J.¹²³⁴⁵^ORCID

Affiliation:

1. JILA

2. National Institute of Standards and Technology

3. University of Colorado

4. Boulder

5. USA

6. Department of Chemistry and Biochemistry

7. The Ohio State University

8. Columbus

Abstract

Sub-Doppler spectroscopy of benzyl radicals reveals how resonance stabilization provides for rovibrationally well resolved and relatively perturbation-free spectra in the CH stretch region.

Funder

Basic Energy Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP05776H

Reference42 articles.

1. Soot formation in shock-tube pyrolysis of toluene, toluene-methanol, toluene-ethanol, and toluene-oxygen mixtures

2. Forming benzene in flames by chemically activated isomerization