Understanding the effects of vicinal carbon substituents and configuration on organofluorine hydrogen-bonding interaction-Reference-Cited by-同舟云学术

Understanding the effects of vicinal carbon substituents and configuration on organofluorine hydrogen-bonding interaction

Published:2018 Issue:68 Volume:8 Page:38980-38986
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Jia Qingqing¹²³⁴,Li Qingzhong⁵⁶⁷⁸⁴^ORCID,Luo Mo¹²³⁴,Li Hai-Bei¹²³⁴^ORCID

Affiliation:

1. School of Ocean

2. Shandong University

3. Weihai 264209

4. People's Republic of China

5. The Laboratory of Theoretical and Computational Chemistry

6. School of Chemistry and Chemical Engineering

7. Yantai University

8. Yantai 264005

Abstract

The vicinal substituents, with gauche/stagger isomer in CH₂XCH₂F and cis/trans isomer in CHXCHF, affect the interaction of C(spⁿ)–F⋯H–O organofluorine hydrogen bonds differently.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shandong Province

Shandong University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA08122K

Reference41 articles.

1. Fluorine in medicinal chemistry

2. Organic fluorine compounds: a great opportunity for enhanced materials properties

3. Catalysis for fluorination and trifluoromethylation

4. C−F Bond Activation in Organic Synthesis

5. Understanding organofluorine chemistry. An introduction to the C–F bond

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