Affiliation:
1. Department of Chemistry, Shaoxing University, Shaoxing, Zhejiang Province, 312000, China
Abstract
[P4442]2[Hy] can simultaneously activate CO2 and 2-aminobenzonitrile due to the two N− sites. The H-bond site of [Hy]2− with 2-aminobenzonitrile is confirmed to be –NH2, and the key reaction intermediate is proposed and the mechanism is reconsidered.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis