Tuneable helices of plasmonic nanoparticles using liquid crystal templates: molecular dynamics investigation of an unusual odd–even effect in liquid crystalline dimers

Author:

Pawlak Mateusz1ORCID,Bagiński Maciej1,Llombart Pablo2ORCID,Beutel Dominik3,González-Rubio Guillermo4ORCID,Górecka Ewa5ORCID,Rockstuhl Carsten36ORCID,Mieczkowski Józef1,Pociecha Damian5ORCID,Lewandowski Wiktor1ORCID

Affiliation:

1. Faculty of Chemistry, University of Warsaw, Ludwika Pasteura 1, 02-093 Warsaw, Poland

2. Departamento de Física Teórica de la Materia Condensada, Instituto Nicolás Cabrera, Universidad Autónoma de Madrid, Madrid, Spain

3. Institute of Theoretical Solid State Physics, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany

4. Physical Chemistry Department of Chemistry, University of Konstanz, Universitätsstraße 10, Box 714, 78457 Konstanz, Germany

5. Faculty of Chemistry, University of Warsaw, Zwirki i Wigury 101, Warsaw 02-089, Poland

6. Institute of Nanotechnology, Karlsruhe Institute of Technology, 76021 Karlsruhe, Germany

Abstract

Liquid crystalline (LC) dimers formed helical nanofilaments depending on the parity of the alkyl linker, revealing an unusual odd–even effect. Doping LC with Au nanoparticles evidenced that helical pitch was regulated by the length of the linker.

Funder

Narodowe Centrum Nauki

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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