Metal-mediated rearrangement of 1,2-diphenylhydrazine to <i>ortho</i>-semidine upon reaction with dichlorotris(triphenylphosphine)ruthenium(<scp>ii</scp>)-Reference-Cited by-同舟云学术

Metal-mediated rearrangement of 1,2-diphenylhydrazine to ortho-semidine upon reaction with dichlorotris(triphenylphosphine)ruthenium(ii)

Published:2022 Issue:83 Volume:58 Page:11673-11676
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cena Nicolas¹^ORCID,Peloquin Andrew J.²^ORCID,Boatz Jerry A.³^ORCID,Costa Sarah⁴,Gralinski Steven R.⁴,Balch Alan L.⁴^ORCID,Ghiassi Kamran B.³^ORCID

Affiliation:

1. HX5, LLC, Air Force Research Laboratory, Aerospace Systems Directorate, Edwards AFB, California 93524, USA

2. Department of Chemistry and Chemistry Research Center, Laboratories for Advanced Materials, United States Air Force Academy, Colorado Springs, Colorado, 80840, USA

3. Air Force Research Laboratory, Aerospace Systems Directorate, Edwards AFB, California 93524, USA

4. Department of Chemistry, University of California, Davis, 95616, USA

Abstract

1,2-Diphenylhydrazine rearranges to ortho-semidine upon reaction with RuCl2(PPh3)3. Crystals of two polymorphs show chiral resolution, producing an enantiopure form, in addition to a racemic, “disappearing” form.

Funder

National Science Foundation

U.S. Air Force

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04500A

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