Synthesis, properties, and crystallization of the alternating stereocopolymer poly(l-lactic acid-alt-d-lactic acid) [syndiotactic poly(lactic acid)] and its blend with isotactic poly(lactic acid)
Author:
Affiliation:
1. Department of Environmental and Life Sciences
2. Graduate School of Engineering
3. Toyohashi University of Technology
4. Toyohashi
5. Japan
Abstract
The alternating stereocopolymer poly(l-lactic acid-alt-d-lactic acid) or syndiotactic poly(lactic acid) was successfully synthesized by the condensation of the l-lactic acid-d-lactic acid dimer.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY00391B
Reference62 articles.
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2. Initiators for the stereoselective ring-opening polymerization of meso-lactide
3. Single site catalysts for stereoselective ring-opening polymerization of lactides
4. Stereoselective Ring-Opening Polymerization of meso-Lactide: Synthesis of Syndiotactic Poly(lactic acid)
5. Stereochemistry of Lactide Polymerization with Chiral Catalysts: New Opportunities for Stereocontrol Using Polymer Exchange Mechanisms
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