From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−-Reference-Cited by-同舟云学术

From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−

Published:2018 Issue:98 Volume:54 Page:13837-13840
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yarovoy Spartak S.¹²³,Smolentsev Anton I.¹²³⁴²,Kozlova Svetlana G.¹²³⁴²,Kompankov Nikolay B.¹²³,Gayfulin Yakov M.¹²³^ORCID,Asanov Igor P.¹²³,Yanshole Vadim V.⁴²³⁵²^ORCID,Mironov Yuri V.¹²³⁴²^ORCID

Affiliation:

1. Nikolaev Institute of Inorganic Chemistry SB RAS

2. 630090 Novosibirsk

3. Russian Federation

4. Novosibirsk State University

5. International Tomography Center SB RAS

Abstract

Two new mixed-valence tungsten cluster anions with bitetrahedral cores, {W₆(μ₄-O)₂(μ₃-CCN)₄} and {W₆(μ₄-O)₂(μ₃-As)₄} were synthesized from WO₃.

Funder

Russian Science Foundation

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC07746K

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