Programmed serial stereochemical relay and its application in the synthesis of morphinans-Reference-Cited by-同舟云学术

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Programmed serial stereochemical relay and its application in the synthesis of morphinans

Published:2017 Issue:10 Volume:8 Page:7031-7037
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ho (Kenny) Park Kun¹²³⁴,Chen Rui¹²³⁴,Chen David Y.-K.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Seoul National University

3. Seoul 151-742

4. South Korea

Abstract

A rationally designed, serial point-to-axial and axial-to-point stereoinduction and its integration into a multi-step and target-oriented organic synthesis was demonstrated in a novel chemical method to access morphinans and it is potentially applicable to other structurally related alkaloids.

Funder

Seoul National University

National Research Foundation of Korea

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC03189K

Reference91 articles.

1. E. M. Carreira and L.Kvaerno, Classics in Stereoselective Synthesis, Wiley-VCH, Weinheim, 2009

2. Reduction of Carbonyl Compounds with Chiral Oxazaborolidine Catalysts: A New Paradigm for Enantioselective Catalysis and a Powerful New Synthetic Method

3. Asymmetric Catalysis: Science and Opportunities (Nobel Lecture) Copyright© The Nobel Foundation 2002. We thank the Nobel Foundation, Stockholm, for permission to print this lecture.

4. Axial-to-central chirality transfer in cyclization processes

5. Recent applications of chiral allenes in axial-to-central chirality transfer reactions

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