Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide-Reference-Cited by-同舟云学术

Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide

Published:2015 Issue:48 Volume:51 Page:9797-9800
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Courtemanche Marc-André¹²³⁴,Pulis Alexander P.⁵⁶⁷⁸,Rochette Étienne¹²³⁴,Légaré Marc-André¹²³⁴,Stephan Douglas W.⁵⁶⁷⁸,Fontaine Frédéric-Georges¹²³⁴

Affiliation:

1. Département de Chimie

2. Université Laval

3. Québec (Québec)

4. Canada, G1V 0A6

5. Department of Chemistry

6. University of Toronto

7. Toronto

8. Canada

Abstract

The FLP species 1-BR₂-2-NMe₂-C₆H₄ (R = 2,4,6-Me₃C₆H₂1, 2,4,5-Me₃C₆H₂2) reacts H₂/CO₂ to give formyl, acetal and methoxy-derivatives.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC03072B

Reference52 articles.

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3. A Well-Defined Iron Catalyst for the Reduction of Bicarbonates and Carbon Dioxide to Formates, Alkyl Formates, and Formamides

4. C–H carboxylation takes gold

5. Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2 Reduction Catalyst

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