Mechanistic insight into the pyridine enhanced α-selectivity in alkyne hydrothiolation catalysed by quinolinolate–rhodium(i)–N-heterocyclic carbene complexes
Author:
Affiliation:
1. Departamento de Química Inorgánica-ISQCH
2. Universidad de Zaragoza-CSIC
3. Zaragoza
4. Spain
5. Departamento de Química Física
6. Universidad de Zaragoza
7. Center of Research Excellence in Petroleum Refining and Petrochemicals
Abstract
Highly Markovnikov-selective RhI–NHC–quinolinolate catalysts in alkyne hydrothiolation are reported.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY01884J
Reference104 articles.
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3. The Emergence of Transition-Metal-Mediated Hydrothiolation of Unsaturated Carbon-Carbon Bonds: A Mechanistic Outlook
4. A. Ogawa , in Topics of Organometallic Chemistry, ed. V. P. Ananikov and M. Tanaka, Springer, Heidelberg, 2013, vol. 43, pp. 325–360
5. Metal-Catalyzed and Metal-Free Alkyne Hydrothiolation: Synthetic Aspects and Application Trends
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