Mechanistic study of styrene aziridination by iron(iv) nitrides

Author:

Crandell Douglas W.12341,Muñoz Salvador B.1234,Smith Jeremy M.1234ORCID,Baik Mu-Hyun56781ORCID

Affiliation:

1. Department of Chemistry

2. Indiana University

3. Bloomington

4. USA

5. Center for Catalytic Hydrocarbon Functionalizations

6. Institute for Basic Science (IBS)

7. Daejeon 34141

8. Republic of Korea

Abstract

A combined experimental and computational investigation reveals that styrene aziridination by an iron(iv) nitride occurs by a stepwise mechanism involving multistate character.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference89 articles.

1. A. Padwa , Aziridines and Azirines: Monocyclic , in Comprehensive Heterocyclic Chemistry III , ed. C. A. Ramsden , E. F. V. Scriven and R. J. K. Taylor , Elsevier , Oxford , 2008 , pp. 1–104

2. Catalytic Ring Expansion Adventures

3. Microwave-Assisted Synthesis and Spectroscopic Properties of 4′-Substituted Rosamine Fluorophores and Naphthyl Analogues

4. Recent developments in asymmetric aziridination

5. C. Botuha , F.Chemla , F.Ferreira and A.Pérez-Luna , Aziridines in Natural Product Synthesis , in Heterocycles in Natural Product Synthesis , ed. K. C. Majumdar and S. K. Chattopadhyay , 2011

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