Cyclic(alkyl)(amino)carbene ruthenium complexes for Z-stereoselective (asymmetric) olefin metathesis

Author:

Morvan Jennifer1ORCID,Vermersch François2ORCID,Lorkowski Jan1ORCID,Talcik Jakub1,Vives Thomas1ORCID,Roisnel Thierry1ORCID,Crévisy Christophe1ORCID,Vanthuyne Nicolas3ORCID,Bertrand Guy2ORCID,Jazzar Rodolphe2ORCID,Mauduit Marc1ORCID

Affiliation:

1. Ecole Nationale Supérieure de Chimie de Rennes, CNRS, ISCR UMR 6226, Univ Rennes, F-35000 Rennes, France

2. UCSD-CNRS Joint Research Chemistry Laboratory (IRL 3555), Department of Chemistry and Biochemistry, University of California, La Jolla, San Diego, California 92093-0358, USA

3. CNRS, iSm2, Centrale Marseille, Aix Marseille Univ, Marseille, France

Abstract

The first Z-stereoselective catechodithiolate ruthenium complexes containing achiral and chiral cyclic(alkyl)(amino)carbene ligands are reported.

Funder

Région Bretagne

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Aix-Marseille Université

University of California, San Diego

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference65 articles.

1. Handbook of Metathesis , ed. R. H. Grubbs , A. G. Wenzel , D. J. O'Leary and E. Khosravi , Wiley-VCH , Weinheim, Germany , 2nd edn, 2015

2. Olefin Metathesis: Theory and Practice , ed. K. Grela , John Wiley & Sons , Hoboken, N. J. , 2014

3. Recent advances in ruthenium-based olefin metathesis

4. Metathesis in Natural Product Synthesis: Strategies, Substrates, and Catalysts , ed. J. Cossy , S. Arseniyadis and C. Meyer , Wiley-VCH , Weinheim, Germany , 2010

5. C.Bruneau and C.Fischmeister , Topics in Organometallic Chemistry, in Alkene Metathesis for Transformations of Renewables in Organometallics for Green Catalysis , ed. P. Dixneuf and J. F. Soulé , Springer , 2018 , vol. 63

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