(NHC)Ni(<scp>ii</scp>)-catalyzed regioselective hydroalkenylation of norbornene derivatives: fine-tuning of NHC ligands and donor alkenes-Reference-Cited by-同舟云学术

(NHC)Ni(ii)-catalyzed regioselective hydroalkenylation of norbornene derivatives: fine-tuning of NHC ligands and donor alkenes

Published:2024 Issue: Volume: Page:
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yu Meng¹²^ORCID,Gu Xiao³²^ORCID,Ho Chun-Yu¹³²^ORCID

Affiliation:

1. Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, (SUSTech), Shenzhen 518055, China

2. Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen 518055, China

3. Shenzhen Grubbs Institute, Southern University of Science and Technology (SUSTech), Shenzhen 518055, China

Abstract

This study introduced a novel cross-hydroalkenylation approach for addressing a resilient challenge in C5-exo-selective norbornene derivative functionalization by using a suitable choice of terminal olefin.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC03258F

Reference30 articles.

1. Catalytic asymmetric Diels Alder reactions

2. S.Kobayashi and K. A.Jorgensen , Cycloaddition Reactions in Organic Synthesis , Wiley-VCH , Weinheim, Cambridge , 2002

3. Y.Hayashi , Cycloaddition Reactions in Organic Synthesis , ed. S. Kobayashi and K. A. Jorgensen , 2002 , pp. 5–55

4. T. V.RajanBabu , in Comprehensive Asymmetric Catalysis , ed. E. N. Jacobsen , A. Pfaltz and H. Yamamoto , Springer , Berlin , 1999 , vol. 1, pp. 417–427

5. C.-Y.Ho and D.Raja , Science of Synthesis , Georg Thieme Verlag KG , 2023 , ch. 47.1.9, vol. 2, pp. 307–389