Binding of carbon dioxide and acetylene to free carboxylic acid sites in a metal–organic framework-Reference-Cited by-同舟云学术

Binding of carbon dioxide and acetylene to free carboxylic acid sites in a metal–organic framework

Published:2024 Issue:21 Volume:15 Page:8197-8203
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Marsh Christopher¹^ORCID,Han Xue¹²,Lu Zhenzhong¹,da Silva Ivan³^ORCID,Cheng Yongqiang⁴,Daemen Luke L.⁴,Day Sarah J.⁵,Thompson Stephen P.⁵,Ramirez-Cuesta Anibal J.⁴^ORCID,Yang Sihai¹⁶^ORCID,Schröder Martin¹^ORCID

Affiliation:

1. Department of Chemistry, University of Manchester, Manchester, M13 9PL, UK

2. College of Chemistry Beijing Normal University, Beijing 100875, China

3. ISIS Neutron and Muon Source, Rutherford Appleton Laboratory, Oxford, OX11 0QX, UK

4. Neutron Scattering Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831, USA

5. Diamond Light Source, Harwell Science Campus, Oxford, OX11 0DE, UK

6. Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Abstract

Metal–organic frameworks incorporating free carboxylic acid and hydroxyl groups are beneficial for selective uptake of small molecules such as CO2 and C2H2. This has been revealed through SXPD and INS/DFT studies.

Funder

H2020 European Research Council

Engineering and Physical Sciences Research Council

Royal Society

University of Manchester

Beijing National Laboratory for Molecular Sciences

Peking University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00101J

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5. Zn(II)-Benzotriazolate Clusters Based Amide Functionalized Porous Coordination Polymers with High CO2 Adsorption Selectivity