Synthesis of 2,3-dihydro-1H-phosphindole-1-oxides via the t-BuLi-mediated rearrangement of vinyl bromides and phosphine oxides-Reference-Cited by-同舟云学术

Synthesis of 2,3-dihydro-1H-phosphindole-1-oxides via the t-BuLi-mediated rearrangement of vinyl bromides and phosphine oxides

Published:2017 Issue:9 Volume:4 Page:1854-1857
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Li Bin¹²³⁴,Zhang Mingkai¹²³⁴,Huang Xulun¹²³⁴,Gu Zhenhua¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Hefei National Laboratory for Physical Sciences at the Microscale

2. University of Science and Technology of China

3. Hefei

4. P. R. China

Abstract

We report an intramolecular vinyllithium addition to phosphine oxides, and discovered an unexpected rearrangement to form unique cyclic phosphine oxides.

Funder

Ministry of Science and Technology of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/QO/C7QO00310B

Reference30 articles.

1. Chiral Monodentate Phosphine Ligand MOP for Transition-Metal-Catalyzed Asymmetric Reactions

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5. Phosphine catalysis of allenes with electrophiles

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