Catalytic applications of small bite-angle diphosphorus ligands with single-atom linkers-Reference-Cited by-同舟云学术

Catalytic applications of small bite-angle diphosphorus ligands with single-atom linkers

Published:2017 Issue:44 Volume:46 Page:15157-15174
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mansell S. M.¹²³⁴^ORCID

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh

4. UK

Abstract

Diphosphorus ligands connected by a single atom (R₂PEPR₂; E = CR₂, CCR₂and NR) give chelating ligands with very small bite-angles as well as enable access to other properties such as bridging modes and hemilability. ThisPerspectivereviews the properties of diphosphorus ligands featuring a single-atom linker and their applications in catalysis, including transformations of alkenes and transfer hydrogenation and hydrogen-borrowing reactions.

Funder

Engineering and Physical Sciences Research Council

Royal Society

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03395H

Reference193 articles.

1. Rational design of diphosphorus ligands – a route to superior catalysts