Application of orthogonal metal–ligand interactions for the synthesis of interpenetrating metallopolymer networks featuring shape-memory and self-healing abilities

Author:

Meurer Josefine12,Bätz Thomas12,Hniopek Julian345ORCID,Bernt Carolin12,Zechel Stefan12,Schmitt Michael34ORCID,Popp Jürgen345ORCID,Hager Martin D.12ORCID,Schubert Ulrich S.124ORCID

Affiliation:

1. Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, Jena 07743, Germany

2. Jena Center of Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, Jena 07743, Germany

3. Institute of Physical Chemistry (IPC), Friedrich Schiller University Jena, Helmholtzweg 4, Jena 07743, Germany

4. Abbe Center of Photonics (ACP), Friedrich Schiller University Jena, Albert-Einstein-Straße 6, Jena 07745, Germany

5. Leibniz Institute of Photonic Technology, e.V. Jena, Albert-Einstein-Straße 9, Jena 07745, Germany

Abstract

This study presents interpenetrating metallopolymer networks (IPNs) based on the orthogonality of two different metal complexes. The synthesized IPNs exhibit excellent shape-memory and self-healing abilities.

Funder

Deutsche Forschungsgemeinschaft

Carl-Zeiss-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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