Tunneling effects in confined gold nanoparticle hydrogenation catalysts-Reference-Cited by-同舟云学术

Tunneling effects in confined gold nanoparticle hydrogenation catalysts

Published:2019 Issue:30 Volume:21 Page:16615-16622
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Luza Leandro¹²³⁴^ORCID,Gual Aitor⁵⁶⁷⁸^ORCID,Fernandes Jesum Alves⁹¹⁰¹¹¹²^ORCID,Eberhardt Dario¹³¹⁴³⁴^ORCID,Dupont Jairton¹²³⁴^ORCID

Affiliation:

1. Laboratory of Molecular Catalysis

2. Universidade Federal do Rio Grande do Sul

3. Porto Alegre

4. Brazil

5. Unitat de Tecnología Química (UTQ)-EURECAT

6. Centre Tecnològic de la Química de Catalunya (CTQC)

7. Tarragona 43007

8. Spain

9. School of Chemistry

10. University of Nottingham

11. Nottingham

12. UK

13. PUCRS

14. Centro Interdisciplinar de Nanociências e Micro-Nanotecnologia

Abstract

H₂ activation proceeds via homolytic activation over AuNPs confined in ionic liquid hybrid supports and display high kinetic isotope effects and convex curves in the Arrhenius plots, which suggests the possible involvement of a tunneling pathway.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

University of Nottingham

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03012C

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