[Ag115S34(SCH2C6H4tBu)47(dpph)6]: synthesis, crystal structure and NMR investigations of a soluble silver chalcogenide nanocluster-Reference-Cited by-同舟云学术

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[Ag115S34(SCH2C6H4tBu)47(dpph)6]: synthesis, crystal structure and NMR investigations of a soluble silver chalcogenide nanocluster

Published:2017 Issue:3 Volume:8 Page:2235-2240
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bestgen Sebastian¹²³⁴,Fuhr Olaf⁵²⁶⁴⁷,Breitung Ben⁵²⁶⁴,Kiran Chakravadhanula Venkata Sei⁵²⁶⁴⁸,Guthausen Gisela⁹¹⁰¹¹³⁴,Hennrich Frank⁵²⁶⁴,Yu Wen¹²¹³¹⁴¹⁵¹⁶,Kappes Manfred M.⁵²⁶⁴¹⁷,Roesky Peter W.¹²³⁴^ORCID,Fenske Dieter¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Karlsruhe Institute of Technology (KIT)

3. 76131 Karlsruhe

4. Germany

5. Institute of Nanotechnology and Karlsruhe Nano Micro Facility (KNMF)

6. 76021 Karlsruhe

7. Lehn-Institute for Functional Materials

8. Helmholtz-Institute Ulm for Electrochemical Energy Storage (HIU)

9. Institute for Water Chemistry and Water Technology

10. Institute for Mechanical Process Engineering and Mechanics

11. Karlsruhe Institute of Technology

12. Zhejiang Provincial Key Laboratory for Chemical and Biochemical Processing Technology of Farm Products

13. School of Biological and Chemical Engineering

14. Zhejiang University of Science and Technology

15. Hangzhou

16. People's Republic of China

17. Institute of Physical Chemistry

Abstract

The soluble 115 nuclear silver cluster [Ag₁₁₅S₃₄(SCH₂C₆H₄^tBu)₄₇(dpph)₆] was synthesized and fully characterized in solution and in the solid state.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04578B

Reference36 articles.

1. Chalcogenide clusters of copper and silver from silylated chalcogenide sources

2. Metal Chalcogenide Clusters on the Border between Molecules and Materials

3. Size-Dependent Optical Spectroscopy of a Homologous Series of CdSe Cluster Molecules

4. Red-luminescent biphosphine stabilized ‘Cu12S6’ cluster molecules

5. Neue Kupfertellurid-Cluster - Synthesen, Kristallstrukturen und optische Spektren

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