A ruthenium cis-dihydride with 2-phosphinophosphinine ligands catalyses the acceptorless dehydrogenation of benzyl alcohol-Reference-Cited by-同舟云学术

A ruthenium cis-dihydride with 2-phosphinophosphinine ligands catalyses the acceptorless dehydrogenation of benzyl alcohol

Published:2021 Issue:38 Volume:50 Page:13407-13411
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Trodden Elizabeth C.¹²,Delve Matthew P.²,Luz Christian²,Newland Robert J.²,Andresen John M.¹,Mansell Stephen M.²^ORCID

Affiliation:

1. Research Centre for Carbon Solutions (RCCS), Heriot-Watt University, Edinburgh, EH14 4AS, UK

2. Institute of Chemical Sciences, School of Engineering and Physical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, UK

Abstract

The first ruthenium dihydride stabilised with phosphinine ligands is described. Formed in situ, it was shown to catalyse the acceptorless dehydrogenation (AD) of benzyl alcohol to benzyl benzoate.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02508B

Reference62 articles.

1. Molecular catalysts for hydrogen production from alcohols

2. Homogeneous Transition Metal Catalysis of Acceptorless Dehydrogenative Alcohol Oxidation: Applications in Hydrogen Storage and to Heterocycle Synthesis

3. Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols

4. Just a Dream—or Future Reality?

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