Square-planar Co(iii) in {O4} coordination: large ZFS and reactivity with ROS-Reference-Cited by-同舟云学术

Square-planar Co(iii) in {O4} coordination: large ZFS and reactivity with ROS

Published:2018 Issue:85 Volume:54 Page:12045-12048
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Steele Jennifer L.¹²³⁴^ORCID,Tahsini Laleh¹²³⁴,Sun Chen¹²³⁴,Elinburg Jessica K.¹²³⁴,Kotyk Christopher M.¹²³⁴^ORCID,McNeely James¹²³⁴,Stoian Sebastian A.⁵⁶⁷⁴^ORCID,Dragulescu-Andrasi Alina⁸⁹¹⁰⁴,Ozarowski Andrew¹¹¹⁰⁴,Ozerov M.¹¹¹⁰⁴,Krzystek J.¹¹¹⁰⁴^ORCID,Telser Joshua¹²¹³¹⁴¹⁵⁴^ORCID,Bacon Jeffrey W.¹²³⁴^ORCID,Golen James A.⁸¹⁶¹⁷¹⁸⁴,Rheingold Arnold L.⁸¹⁶¹⁷¹⁸⁴,Doerrer Linda H.¹²³⁴^ORCID

Affiliation:

1. Chemistry Department

2. Boston University

3. Boston

4. USA

5. Department of Chemistry

6. University of Idaho

7. Moscow

8. Department of Chemistry and Biochemistry

9. Florida State University

10. Tallahassee

11. National High Magnetic Field Laboratory, Florida State University

12. f Department of Biological

13. Chemical and Physical Sciences

14. Roosevelt University

15. Chicago

16. University of California

17. San Diego

18. La Jolla

Abstract

Oxidation of distorted square-planar perfluoropinacolate Co compound [Co^II(pin^F)₂]²⁻, 1, to [Co^III(pin^F)₂]¹⁻, 2, is reported.

Funder

Division of Materials Research

Basic Energy Sciences

Division of Chemistry

Boston University

University of Idaho

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC04464C

Reference30 articles.

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