Chlorinated polyhedral selenaboranes revisited by joint experimental/computational efforts: the formation of closo-1-SeB9Cl9 and the crystal structure of closo-SeB11Cl11-Reference-Cited by-同舟云学术

Chlorinated polyhedral selenaboranes revisited by joint experimental/computational efforts: the formation of closo-1-SeB₉Cl₉ and the crystal structure of closo-SeB₁₁Cl₁₁

Published:2023 Issue:45 Volume:52 Page:16886-16893
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Keller Willi¹,Hofmann Matthias²,Wadepohl Hubert²,Enders Markus²^ORCID,Fanfrlík Jindřich³^ORCID,Hnyk Drahomír⁴^ORCID

Affiliation:

1. Institut für Chemie, Universität Hohenheim, Garbenstrasse 30, 70599 Stuttgart, Germany

2. Anorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany

3. Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Praha 6, Czech Republic

4. Institute of Inorganic Chemistry of the Czech Academy of Sciences, 250 68 Husinec-Řež, Czech Republic

Abstract

The newly generated closo-1-SeB9Cl9 and the crystal structure of closo-SeB11Cl11 were investigated, the latter due to the presence of a σ-hole on Se, thus forming a strong chalcogen bond.

Funder

Deutsche Forschungsgemeinschaft

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02987E

Reference40 articles.

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