Observation of the single-ion magnet behavior of d8 ions on two-coordinate Co(i)

Observation of the single-ion magnet behavior of d8 ions on two-coordinate Co(i)–NHC complexes

Published:2015 Issue:12 Volume:6 Page:7156-7162
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Meng Yin-Shan¹²³⁴⁵,Mo Zhenbo⁶⁷⁸⁹¹⁰,Wang Bing-Wu¹²³⁴⁵^ORCID,Zhang Yi-Quan¹¹¹²¹³¹⁴¹⁰,Deng Liang⁶⁷⁸⁹¹⁰,Gao Song¹²³⁴⁵

Affiliation:

1. Beijing National Laboratory of Molecular Science

2. State Key Laboratory of Rare Earth Materials Chemistry and Applications

3. College of Chemistry and Molecular Engineering

4. Peking University

5. Beijing 100871

6. State Key Laboratory of Organometallic Chemistry

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

10. P. R. China

11. Jiangsu Key Laboratory for NSLSCS

12. School of Physical Science and Technology

13. Nanjing Normal University

14. Nanjing 210023

Abstract

The first single-ion magnet (SIM) [Co(IMes)₂][BPh₄] (IMes: 1,3-dimesitylimidazol-2-ylidene) with d⁸ electronic configuration has been found in two-coordinate Co(i)–NHC complexes.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02611C

Reference54 articles.

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3. Electronic Structure and Reactivity of Three-Coordinate Iron Complexes

4. Stable Two-Coordinate, Open-Shell (d1–d9) Transition Metal Complexes

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