Probing how Ti- and Nb-substitution affect the stability and improve the electrochemical performance of β- and ε-LiVOPO4

Author:

Hidalgo Marc Francis V.1ORCID,Buyuker Isik Su1,Kamm Gabrielle E.2ORCID,Zhu Zhuoying3ORCID,Grenier Antonin2,Zuba Mateusz J.1,Deng Zhi3,Zong Yanxu4,Kaplan Carol1ORCID,Chernova Natasha A.1ORCID,Zhou Guangwen4ORCID,Piper Louis F. J.1ORCID,Ong Shyue Ping3ORCID,Chapman Karena W.2,Whittingham M. S.1

Affiliation:

1. NECCES, Binghamton University, Binghamton, NY 13902, USA

2. Department of Chemistry, Stony Brook University, NY 11794, USA

3. Department of NanoEngineering, University of California San Diego, 9500 Gilman Drive #0448, La Jolla, CA 92093, USA

4. Materials Science and Engineering Program, Department of Mechanical Engineering, State University of New York, Binghamton, New York 13902, USA

Abstract

LiVOPO4 is a promising next-generation multi-electron cathode material, boasting a theoretical capacity of 305 mA h g−1, significantly higher than any commercially used Li-ion battery cathode material.

Funder

U.S. Department of Energy

Office of Science

Basic Energy Sciences

University of California

National Science Foundation

New York State Energy Research and Development Authority

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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