Base-catalyzed addition of silylacetylenes to ketones: a route to protected tertiary propargyl alcohols-Reference-Cited by-同舟云学术

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Base-catalyzed addition of silylacetylenes to ketones: a route to protected tertiary propargyl alcohols

Published:2023 Issue:11 Volume:10 Page:2752-2759
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Kuciński Krzysztof¹^ORCID,Łuczak Alicja¹,Mankouski Aliaksei¹,Hreczycho Grzegorz¹^ORCID

Affiliation:

1. Faculty of Chemistry, Adam Mickiewicz University, Poznań, Uniwersytetu Poznańskiego St. 8, 61-614 Poznań, Poland

Abstract

Novel protocol for base-catalyzed addition of silylacetylenes to ketones – exceptional scope, gram scale and derivatization.

Funder

Uniwersytet im. Adama Mickiewicza w Poznaniu

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00579H

Reference60 articles.

1. Brønsted Acid Promoted Sulfonylation of Propargylic Alcohols: Synthesis of Triaryl Allenyl Sulfones under Mild Conditions

2. A review towards synthesis of heterocycles using propargyl alcohols and propargyl amines

3. Selective 5‐Exo‐Dig versus 6‐Endo‐Dig Cyclization of Benzoimidazole Thiols with Propargyl Alcohols

4. Recent approaches for the synthesis of pyridines and (iso)quinolines using propargylic Alcohols

5. Relay Rhodium(I)/Acid Catalysis for Rapid Access to Benzo‐2 H ‐Pyrans and Benzofurans

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