Ring-opening polymerization of ε-caprolactone mediated by a di-zinc complex bearing a macrocyclic thioether-phenolate [OSSO]-type ligand-Reference-Cited by-同舟云学术

Ring-opening polymerization of ε-caprolactone mediated by a di-zinc complex bearing a macrocyclic thioether-phenolate [OSSO]-type ligand

Published:2022 Issue:20 Volume:13 Page:2971-2979
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Chen Junwu¹^ORCID,Wu Xianmin¹,Zhang Li¹,Duan Zhongyu¹,Liu Binyuan¹^ORCID

Affiliation:

1. Hebei Key Laboratory of Functional Polymer, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

Abstract

A unique example of zinc bromide complexes bearing a macrocyclic [OSSO]-type thioetherphenolate ligand has been successfully explored toward ring-opening polymerization of ε-caprolactone in the presence of epoxides and onium salts.

Funder

Natural Science Foundation of Hebei Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00115B

Reference47 articles.

1. The return of a forgotten polymer—Polycaprolactone in the 21st century

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3. Design, functionalization strategies and biomedical applications of targeted biodegradable/biocompatible polymer-based nanocarriers for drug delivery

4. Bioinspired polymer vesicles and membranes for biological and medical applications

5. Comparison of the degradation of polycaprolactone and polycaprolactone–(β-tricalcium phosphate) scaffolds in alkaline medium

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