Gibbs free energy of liquid water derived from infrared measurements
Author:
Affiliation:
1. Institut des Sciences de la Terre d'Orléans
2. UMR 7327 Université d'Orléans/CNRS/BRGM
3. 45071 Orléans cedex, France
4. Synchrotron SOLEIL
5. L'Orme des Merisiers Saint Aubin
6. 91192 Gif-sur-Yvette, France
Abstract
A completely new set of IR bands of liquid water from 4 cm−1 to 4000 cm−1 is studied from spectroscopic and thermodynamic viewpoints over a large thermal range, evidencing the so-called isosbestic points on the different absorption bands.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP03466J
Reference56 articles.
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2. The physics of liquid water
3. Y. Maréchal , The Hydrogen Bond and the Water Molecule: The Physics and Chemistry of Water, Aqueous and Bio Media , Elsevier , Amsterdam , 2007 , p. 318
4. Effect of ions on the structure of water
5. Structure and dynamics of hydrated ions
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