Quasiliving carbocationic polymerization of isobutylene using FeCl3 as an efficient and water-tolerant Lewis acid: synthesis of well-defined telechelic polyisobutylenes

Author:

Bohdan Mikalai12,Shiman Dmitriy I.12,Nikishau Pavel A.1ORCID,Vasilenko Irina V.1,Kostjuk Sergei V.12ORCID

Affiliation:

1. Research Institute for Physical Chemical Problems of the Belarusian State University, Leningradskaya St. 14, 220006, Minsk, Belarus

2. Department of Chemistry, Belarusian State University, Leningradskaya St. 14, 220006, Minsk, Belarus

Abstract

A cost-efficient approach for the preparation of well-defined low molecular weight difunctional polyisobutulenes possessing an exo-olefin or hydroxyl group was developed in this study.

Funder

BASF

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Reference69 articles.

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2. Modern cationic vinyl polymerization

3. Macromolecular Engineering via Carbocationic Polymerization: Branched Structures, Block Copolymers and Nanostructures

4. P.De and R.Faust , Macromolecular Engineering. Precise Synthesis, Materials properties, Applications , Wiley , Weinheim , 2007 , vol. 1

5. A Renaissance in Living Cationic Polymerization

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