Trace ethylene carbonate-mediated low-concentration ether-based electrolytes for high-voltage lithium metal batteries

Author:

Chen Yinghua12,Ma Zheng1,Wang Yuqi1,Kumar Pushpendra3,Zhao Fei1,Cai Tao1,Cao Zhen4,Cavallo Luigi4ORCID,Cheng Haoran1,Li Qian1,Ming Jun12ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei, 230026, China

3. School of Physical Sciences, Jawaharlal Nehru University, New Delhi, 110067, India

4. KAUST Catalysis Center, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

Abstract

A solubilization and stabilization effect of trace ethylene carbonate solvent assisted by the varied molecule-ion interaction was discovered in ether-based electrolyte, enabling the 80 μm Li || LiNi0.8Co0.1Mn0.1O2 full-cell operate at 4.5 V stably.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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