Enhanced electrochemical CO2-to-ethylene conversion through second-shell coordination on a Cu single-atom catalyst

Author:

Shen Yi12ORCID,Pan Yongliang1,Xiao Huanyong1,Zhang Haizhong1,Zhu Chao1,Fang Qile3,Li Yungui4,Lu Lun5,Ye Liqun6ORCID,Song Shuang1ORCID

Affiliation:

1. College of Environment, Zhejiang University of Technology, Hangzhou, 310032, P. R. China

2. Shaoxing Research Institute, Zhejing University of Technology, Shaoxing, 312000, P. R. China

3. Advanced Institute of Natural Sciences, Beijing Normal University at Zhuhai, Zhuhai, 519087, P. R. China

4. Sichuan Provincial Sci-Tech Cooperation Base of Low-cost Wastewater Treatment Technology, Department of Environmental Engineering, Southwest University of Science and Technology, Mianyang, 621010, P. R. China

5. State Environmental Protection Key Laboratory of Environmental Pollution Health Risk Assessment, South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou, 510655, P. R. China

6. College of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, 443002, P. R. China

Abstract

The electrocatalytic CO2 reduction reaction (CO2RR) utilizing Cu single-atom catalyst modulation through second-shell S coordination (Cu–C3N4–S) achieves predominant catalytic activity with high C2H4 faradaic efficiency at low potentials.

Funder

Postdoctoral Research Foundation of China

National Natural Science Foundation of China

Fundamental Research Funds for the Provincial Universities of Zhejiang

Natural Science Foundation of Zhejiang Province

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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