Asymmetric epoxidation of enones: effect of surfactants, radical scavengers and morphology of catalysts on reaction rates, chemical yields and enantioselectivities in phase-transfer catalysis-Reference-Cited by-同舟云学术

Asymmetric epoxidation of enones: effect of surfactants, radical scavengers and morphology of catalysts on reaction rates, chemical yields and enantioselectivities in phase-transfer catalysis

Published:2022 Issue:18 Volume:9 Page:4902-4909
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lee Geumwoo¹,Lee Jeong-Hee¹,Lee Jaeyong¹,Ha Min Woo²,Kim Mi-hyun³^ORCID,Hong Suckchang¹^ORCID,Park Hyeung-geun¹^ORCID

Affiliation:

1. Research Institute of Pharmaceutical Sciences and College of Pharmacy, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Republic of Korea

2. Jeju Research Institute of Pharmaceutical Sciences, College of Pharmacy, Jeju National University, Jeju 63243, Republic of Korea

3. College of Pharmacy, Gachon University, 191 Hambakmoero, Yeonsu-gu, Incheon 21936, Republic of Korea

Abstract

Highly enantioselective epoxidation of enones has been accomplished with asymmetric phase-transfer catalysis using Cinchona alkaloid-derived meta-dimer catalysts.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D2QO00924B

Reference34 articles.

1. The first practical method for asymmetric epoxidation

2. Catalytic asymmetric epoxidation and kinetic resolution: modified procedures including in situ derivatization

3. Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

4. The Enantioselective Synthesis of α-Amino Acids by Phase-Transfer Catalysis with Achiral Schiff Base Esters

5. Cinchona-based phase-transfer catalysts for asymmetric synthesis

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