Synthesis, structure, and characterisation of a ferromagnetically coupled dinuclear complex containing Co(<scp>ii</scp>) ions in a high spin configuration and thiodiacetate and phenanthroline as ligands and of a series of isomorphous heterodinuclear complexes containing different Co : Zn ratios-Reference-Cited by-同舟云学术

Synthesis, structure, and characterisation of a ferromagnetically coupled dinuclear complex containing Co(ii) ions in a high spin configuration and thiodiacetate and phenanthroline as ligands and of a series of isomorphous heterodinuclear complexes containing different Co : Zn ratios

Published:2023 Issue:40 Volume:52 Page:14595-14605
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pérez Ana L.¹²^ORCID,Kemmerer Axel¹^ORCID,Zapata Alejandro J.¹^ORCID,Sartoris Rosana¹,Gonzalez Pablo J.¹^ORCID,Urteaga Raul²³^ORCID,Baggio Ricardo⁴,Suarez Sebastián⁴^ORCID,Ramos Carlos A.⁵,Dalosto Sergio D.²³,Rizzi Alberto C.¹,Brondino Carlos D.¹^ORCID

Affiliation:

1. Departamento de Física, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral and CONICET, Ciudad Universitaria, S3000ZAA Santa Fe, Argentina

2. Instituto de Física del Litoral, Universidad Nacional del Litoral – CONICET, Güemes 3450, 3000 Santa Fe, Argentina

3. Facultad de Ingeniería Química, Universidad Nacional del Litoral, Santiago del Estero 2829, 3000 Santa Fe, Argentina

4. Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Buenos Aires, Argentina

5. Instituto de Nanociencia y Nanotecnología, CNEA-CONICET, Centro Atómico Bariloche, 8400, San Carlos de Bariloche, Río Negro, Argentina

Abstract

Increasing concentrations of Co(ii) ions unveil the spin state of the solid state lattice.

Funder

Ministerio de Ciencia, Tecnología e Innovación Productiva

Consejo Nacional de Investigaciones Científicas y Técnicas

Universidad Nacional del Litoral

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02115G

Reference80 articles.

1. Zwitterionic Cobalt Complexes with Bis(diphenylphosphino)(N-thioether)amine Assembling Ligands: Structural, EPR, Magnetic, and Computational Studies

2. A high-frequency EPR study of magnetic anisotropy and intermolecular interactions of Co(II) ions

3. Spectroscopic and Magnetic Studies of Co(II) Scorpionate Complexes: Is There a Halide Effect on Magnetic Anisotropy?

4. Three new cobalt(II) coordination polymers based on 1,3-bis(4-pyridyl)propane: Syntheses, structures and magnetic properties

5. Homospin single-chain magnet with 1D ferromagnetic azido-cobalt Ising-type chain

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