Signature of a conical intersection in the dissociative photoionization of formaldehyde-Reference-Cited by-同舟云学术

Signature of a conical intersection in the dissociative photoionization of formaldehyde

Published:2020 Issue:23 Volume:22 Page:12886-12893
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zanchet Alexandre¹²³⁴⁵^ORCID,García Gustavo A.⁶⁷⁸⁹^ORCID,Nahon Laurent⁶⁷⁸⁹^ORCID,Bañares Luis¹²³⁴⁵,Marggi Poullain Sonia¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Física (Unidad Asociada de I+D+i al CSIC)

2. Facultad de Ciencias Químicas

3. Universidad Complutense de Madrid

4. 28040 Madrid

5. Spain

6. Synchrotron SOLEIL

7. L'Orme des Merisiers

8. 91192 Gif sur Yvette

9. France

Abstract

Electron/ion coincidence experiments and ab initio calculations of the dissociative photoionization of formaldehyde reveal the presence of a conical intersection controlling the dynamics and favoring dissociation into the molecular channel, CO⁺ + H₂.

Funder

Ministerio de Ciencia e Innovación

H2020 Marie Skłodowska-Curie Actions

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP01267J

Reference25 articles.

1. A Systematic Study of Glycolaldehyde in Sagittarius B2(N) at 2 and 3 mm: Criteria for Detecting Large Interstellar Molecules