Metal-free reduction of the greenhouse gas sulfur hexafluoride, formation of SF5 containing ion pairs and the application in fluorinations
Author:
Affiliation:
1. King Abdullah University of Science and Technology (KAUST)
2. KAUST Catalysis Center (KCC)
3. Thuwal
4. 23955-6900 Saudi Arabia
5. RWTH Aachen University
6. Institut für Technische und Makromolekulare Chemie
7. D-52074 Aachen
8. Germany
Abstract
A protocol for the fast and selective two-electron reduction of the potent greenhouse gas sulfur hexafluoride (SF6) by organic electron donors at ambient temperature has been developed.
Publisher
Royal Society of Chemistry (RSC)
Subject
Pollution,Environmental Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/GC/C7GC00877E
Reference84 articles.
1. NIOSH Pocket Guide to Chemical Hazards, No 0576, http://www.cdc.gov/niosh/npg/npgd0576.html
2. F. Jakob and N.Perjanik, in Sulfur Hexafluoride, A Unique Dielectric, Analytical ChemTech International, Inc., 1998
3. Sulfur hexafluoride and the electric power industry
4. Recent trend and future perspectives in electrical insulation techniques in relation to sulfur hexafluoride (SF6) substitutes for high voltage electric power equipment
5. Characterisation of protective surface films formed on molten magnesium protected by air/SF6 atmospheres
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