Remarkable increase in the rate of the catalytic epoxidation of electron deficient styrenes through the addition of Sc(OTf)3 to the MnTMTACN catalyst

Author:

Nodzewska Aneta12345ORCID,Watkinson Michael12345ORCID

Affiliation:

1. The Joseph Priestley Building

2. School of Biological and Chemical Sciences

3. Queen Mary University of London

4. London

5. UK

Abstract

Sc(OTf)3 produces a remarkable enhancement in the activity of the MnTMTACN catalyst in the epoxidation of electron deficient styrenes.

Funder

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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3. A. Archelas , G.Iacazio and M.Kotik , Epoxide Hydrolases and their Application in Organic Synthesis [in] Green Biocatalysis , ed. R. N. Patel , John Wiley & Sons, Inc. , Hoboken , 2016 , pp 179–229

4. Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivatives

5. Ring-Opening Polymerization of Epoxides: Facile Pathway to Functional Polyethers via a Versatile Organoaluminum Initiator

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