Boron Lewis acid-catalyzed formal insertion of isocyanides into a C–O bond of benzyl esters-Reference-Cited by-同舟云学术

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Boron Lewis acid-catalyzed formal insertion of isocyanides into a C–O bond of benzyl esters

Published:2023 Issue:17 Volume:10 Page:4381-4387
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xu Tong-Tong¹^ORCID,Xiao Yuanjiu¹^ORCID,Zhou Jin-Lan¹^ORCID,Tang Lei¹^ORCID,Wu Feng¹^ORCID,Sheng Jiang-Yi-Hui¹^ORCID,Wu Wen-Biao¹^ORCID,Feng Jian-Jun¹^ORCID

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan Provincial Key Laboratory of Animal Models and Molecular Medicine, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, P. R. China

Abstract

A boron Lewis acid catalyzed cascade process consisting of a rare isocyanide insertion with benzyl esters and the Mumm rearrangement to afford valuable imides with 100% atom utilization.

Funder

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00944K

Reference85 articles.

1. Main-group elements as transition metals

2. Reversible Insertion of Unactivated Alkenes into Silicon(II)-Tin Bonds

3. Transition‐Metal‐Like Catalysis with a Main‐Group Element: Bismuth‐Catalyzed C−F Coupling of Aryl Boronic Esters

4. Catalysis, FLPs, and Beyond

5. Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15

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