Stereoselective synthesis of enantiomerically pure bowl-shaped hydroxytribenzotriquinacenes

Author:

Rommelmann Philipp1234,Nachtigall Beate1234,Guntelmann Tim1234,Gröger Harald12345ORCID,Kuck Dietmar12345ORCID

Affiliation:

1. Department of Chemistry

2. Bielefeld University

3. 33615 Bielefeld

4. Germany

5. Center for Molecular Materials (CM2)

Abstract

A bowl-shaped (M)-2-hydroxytribenzotriquinacene was obtained in enantiomerically pure form by stereoselective enzyme-catalysed ester hydrolysis of the racemic TBTQ-based aryl acetate.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Cited by 6 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Benzoannellated Fenestranes Bearing para ‐Terphenyl Units;European Journal of Organic Chemistry;2021-11-23

2. Dual-Mode Chiral Self-Assembly of Cone-Shaped Subphthalocyanine Aromatics;Journal of the American Chemical Society;2020-11-13

3. Chiral Derivatives of 2-Aminotribenzotriquinacene: Synthesis and Optical Resolution;The Journal of Organic Chemistry;2020-04-09

4. Solvent-Controlled Racemic Resolution of C3-Symmetric Trihydroxytribenzotriquinacenes;The Journal of Organic Chemistry;2020-01-28

5. Enantioselective Electrophilic Aromatic Nitration: A Chiral Auxiliary Approach;Angewandte Chemie International Edition;2018-12-17

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