Effects of interfacial specific cations and water molarities on AOT micelle-to-vesicle transitions by chemical trapping: the specific ion-pair/hydration model

Author:

Liu Changyao1234ORCID,Wang Yuzhao1234,Gao Yanfei1234,Zhang Yongliang567,Zhao Li1234ORCID,Xu Baocai1234,Romsted Laurence S.567ORCID

Affiliation:

1. School of Food and Chemical Engineering

2. Beijing Technology and Business University

3. Beijing

4. People's Republic of China

5. Department of Chemistry and Chemical Biology, Rutgers

6. The State University of New Jersey

7. USA

Abstract

Added salts induce micelle-to-vesicle transitions at specific cation concentrations in Hofmeister order by forming polar headgroup–counterion pairs that release water.

Funder

National Natural Science Foundation of China

National Science Foundation

Beijing Technology and Business University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference78 articles.

1. M. J. Rosen , Surfactants and interfacial phenomena , John Wiley & Sons , New York , 2004

2. D. F. Evans and H.Wennerström , The colloidal domain: where physics, chemistry, biology, and technology meet , VCH Publishers , New York , 1994

3. B. Kronberg and B.Lindman , Surfactants and polymers in aqueous solution , John Wiley & Sons Ltd , Chichester , 1998

4. K. L. Mittal and D. O.Shah , Adsorption and aggregation of surfactants in solution , CRC Press , Raton , 2003

5. B. W. Ninham and P. L.Nostro , Molecular forces and self assembly: in colloid, nano sciences and biology , Cambridge University Press , Cambridge , 2010

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