Dialumenes – aryl vs. silyl stabilisation for small molecule activation and catalysis
Author:
Affiliation:
1. Department of Chemistry
2. Catalysis Research Center and Institute of Silicon Chemistry
3. Technische Universität München
4. Garching bei München
5. Germany
Abstract
Ligand controlled reactivity: a trans-bent and twisted geometry enables dihydrogen activation and enhanced catalytic activity for NHC-stabilised dialumenes.
Funder
H2020 European Research Council
H2020 Marie Skłodowska-Curie Actions
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01561J
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5. Synthesis and structure of bis(2,4,6-tri-tert-butylphenyl)diphosphene: isolation of a true phosphobenzene
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