Finding a soft spot for vanadium: a P-bound OCP ligand-Reference-Cited by-同舟云学术

Finding a soft spot for vanadium: a P-bound OCP ligand

Published:2019 Issue:42 Volume:55 Page:5966-5969
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Grant Lauren N.¹²³⁴^ORCID,Krzystek J.⁵⁶⁷⁴,Pinter Balazs¹⁸⁹¹⁰,Telser Joshua¹¹¹²¹³¹⁴⁴^ORCID,Grützmacher Hansjörg¹⁵¹⁶¹⁷¹⁸^ORCID,Mindiola Daniel J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Pennsylvania

3. Philadelphia

4. USA

5. National High Magnetic Field Laboratory

6. Florida State University

7. Tallahassee

8. Universidad Técnica Federico Santa María

9. Valparaíso

10. Chile

11. Department of Biological

12. Physical and Health Sciences

13. Roosevelt University

14. Chicago

15. Department of Chemistry and Applied Biosciences

16. ETH Zürich

17. Hönggerberg

18. Switzerland

Abstract

The first example of a P-bound phosphaethynolato ligand, [OCP]⁻, to an early 3d transition metal is presented, along with detailed characterization by single crystal X-ray diffraction, SQuID magnetometry, HFEPR spectroscopy, and computational studies.

Funder

National Science Foundation

University of Pennsylvania

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC01500K

Reference36 articles.

1. Phosphination of Carbon Monoxide: A Simple Synthesis of Sodium Phosphaethynolate (NaOCP)

2. The 2-Phosphaethynolate Anion: A Convenient Synthesis and [2+2] Cycloaddition Chemistry

3. The Chemistry of the 2‐Phosphaethynolate Anion

4. A General Synthesis of Phosphorus‐ and Arsenic‐Containing Analogues of the Thio‐ and Seleno‐cyanate Anions

5. A Scandium‐Stabilized Diisophosphaethynolate Ligand: [OCPPCO] 4−

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