Bandgap-adjustment and enhanced surface photovoltage in Y-substituted LaTaIVO2N

Author:

Bubeck Cora12345ORCID,Widenmeyer Marc1234,De Denko Alexandra T.6789,Richter Gunther1011124,Coduri Mauro131415616ORCID,Colera Eduardo Salas1314151718,Goering Eberhard19124,Zhang Hongbin1202134,Yoon Songhak22234,Osterloh Frank E.6789ORCID,Weidenkaff Anke1234

Affiliation:

1. Technical University of Darmstadt

2. Department of Materials and Earth Sciences, Materials and Resources

3. 64287 Darmstadt

4. Germany

5. University of Stuttgart

6. Department of Chemistry

7. University of California

8. Davis

9. USA

10. Central Scientific Facility Materials

11. Max Planck Institute for Intelligent Systems

12. 70569 Stuttgart

13. European Synchrotron Radiation Facility (ESRF)

14. 38000 Grenoble

15. France

16. University of Pavia

17. Universidad Carlos III de Madrid (UC3M)

18. Department of Physics

19. Max Planck Institute for Intelligent Systems, Modern Magnetic Systems

20. Department of Materials and Earth Sciences

21. Theory of Magnetic Materials

22. Fraunhofer IWKS

23. 63457 Hanau

Abstract

Microstructure controlled ammonolysis allowed the synthesis of oxynitrides La1−xYxTaIVO2N (x ≤ 0.3) and YTa(O,N)3 of which the first ones showed a remarkable up-built of photovoltage even in the presence of reduced tantalum (e.g. Ta4+).

Funder

U.S. Department of Energy

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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