Th@C2(8)-C84 and Th@Cs(15)-C84: impact of actinide metal ions on the electronic structures of actinide endohedral metallofullerenes-Reference-Cited by-同舟云学术

Th@C₂(8)-C₈₄ and Th@C_s(15)-C₈₄: impact of actinide metal ions on the electronic structures of actinide endohedral metallofullerenes

Published:2023 Issue:23 Volume:10 Page:6901-6908
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Cao Tiantian¹²,Meng Qingyu²,Fu Ze²,Shen Yi²,Yan Yingjing²,Wang Qin²,Zhao Bing¹,Wang Wenxia¹,Merimi Khaoula³,Rodríguez-Fortea Antonio³^ORCID,Yao Yang-Rong⁴^ORCID,Chen Ning²^ORCID

Affiliation:

1. Suzhou Institute of Trade and Commerce, 287 Xuefu Road, Suzhou, 215009, China

2. College of Chemistry, Chemical Engineering and Materials Science, and State Key Laboratory of Radiation Medicine and Protection, Soochow University, Suzhou, Jiangsu 215123, P. R. China

3. Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, 43007 Tarragona, Spain

4. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Abstract

Two novel endohedral metallofullerenes, Th@C2(8)-C84 and Th@Cs(15)-C84, have been successfully synthesized and fully characterized. Spectroscopic studies suggest that endohedral actinide metal atoms have an important impact on the electronic structures of actinide metallofullerenes.

Funder

Natural Science Research of Jiangsu Higher Education Institutions of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Generalitat de Catalunya

Universitat Rovira i Virgili

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Ministerio de Ciencia e Innovación

Natural Science Foundation of Jiangsu Province

Natural Science Foundation of Anhui Province

Publisher

Royal Society of Chemistry (RSC)