Determination of the semiexperimental equilibrium structure of 2-acetylthiophene in the presence of methyl internal rotation and substituent effects compared to thiophene-Reference-Cited by-同舟云学术

Determination of the semiexperimental equilibrium structure of 2-acetylthiophene in the presence of methyl internal rotation and substituent effects compared to thiophene

Published:2022 Issue:6 Volume:24 Page:3804-3815
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Dindić Christina¹^ORCID,Ludovicy Jil¹^ORCID,Terzi Vladimir¹,Lüchow Arne¹^ORCID,Vogt Natalja²³^ORCID,Demaison Jean²^ORCID,Nguyen Ha Vinh Lam⁴⁵^ORCID

Affiliation:

1. Institute of Physical Chemistry, RWTH Aachen University, Landoltweg 2, Aachen 52074, Germany

2. Section of Chemical Information Systems, University of Ulm, Albert-Einstein-Allee 47, Ulm 89081, Germany

3. Department of Inorganic Chemistry, Lomonosov Moscow State University, Moscow 119991, Russian Federation

4. Univ Paris Est Creteil and Université de Paris, CNRS, LISA, Créteil 94010, France

5. Institut Universitaire de France (IUF), Paris cedex 05 75231, France

Abstract

The microwave spectra of thiophene and 2-acetylthiophene were recorded and analysed. The semiexperimental equilibrium structure of the syn conformer of 2-acetylthiophene was precisely determined and compare with that of thiophene.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D1CP04478H

Reference69 articles.

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